Vray For Macbook

Keep having serious major problems with my Sketchup and Vray models.

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I'm currently modelling a large office interior and its been fully modelled and I've started to add Vray materials - most of them downloaded from Chaos and FlyingArchitect (all placed in the same folder on my desktop) - all been going well until I start to render - major crashing happens and then every time I reopen the model all goes well until Vray starts to reload the materials - BANG it crashes. So now I can't even open the weeks work I've done - bugger.
I'm using the most recent Sketchup and Vray - so really a bit annoyed as I've spent a bit of money purchasing these two products - and now its costing me time and effort - which is a shame as I enjoy using both products and produce brilliant results.
The size of the sketch up model is 75meg - is this a problem?
This is the latest vas report but I've had plenty of these this morning
System Information
platform = darwin
country = UnitedKingdom
language = English
Made it after UIManager.initialize
/Library/Frameworks/ASGVIS.framework/Versions/A/Frameworks/Python.framework/Versions/2.6/lib/python2.6/site-packages/Ft/Xml/InputSource.py:346: DeprecationWarning: functions overriding warnings.showwarning() must support the 'line' argument
Vray FtWarning, 2)
FtWarning: Creation of InputSource without a URI
My mac is a 2.93Ghz Intel Core i7 with 16 GB of memory so the machines up for the task.
Any help or more info required can be provided.
Just need to find out what the problem is so I can understand why this is happening and if there's anything in the future I can do to my models and render settings to make my work less frustrating.
Drew